Ukrainian Journal of Physical Optics 

Home page
 
 

Other articles 

in this issue
Optical properties of ZnO:TM (TM = Cr, Mn and Co) layers obtained by pulsed laser deposition technique

1Potera P., 1,2Virt I., 1Cieniek B. and 1Wisz G.

1Faculty of Mathematics and Natural Sciences University of Rzeszow, Aleja Tadeusza Rejtana 16C, 35-310, Rzeszów Rzeszow, Poland
2Drohobych State Pedagogical University, Ivan Franko Str., 24, Drohobych, 82100, Ukraine 

Download this article

Abstract. We study the optical properties of zinc-chromium (ZnCrO), zinc-manganese (ZnMnO) and zinc-cobalt (ZnCoO) oxide layers grown on sapphire substrates, using a pulsed laser deposition technique. The influence of target composition and post-growth annealing on the optical transmission of the films and their bandgap energy are analyzed.

Keywords: zinc oxides, pulsed laser deposition, optical transmission spectra

UDC: 535.343.2
Ukr. J. Phys. Opt. 20 143-150
doi: 10.3116/16091833/20/4/143/2019
Received: 23.07.2019

Анотація.  Вивчено оптичні властивості шарів цинково-хромового (ZnCrO), цинково-марганцевого (ZnMnO) і цинково-кобальтового (ZnCoO) оксидів, вирощених на сапфірових підкладках, використовуючи техніку імпульсну лазерного висадження. Проаналізовано вплив вихідного складу та післяростового відпалу на оптичне пропускання плівок і їхню ширину забороненої зони.

REFERENCES
  1. Lee JH, Ko KH, Park BO, 2003. Electrical and optical properties of ZnO transparent conducting films by the sol-gel method. Journ.Cryst.Growth, 247: 119-125. doi:10.1016/S0022-0248(02)01907-3
  2. Virt IS, Hadzaman IV, Bilyk IS, Rudyi IO, Kurilo IV, Frugynskyi MS, Potera P, 2010. Properties of ZnO and ZnMnO thin films obtained by pulsed laser ablation. Acta Physica Polonica A, 117: 34-37. doi:10.12693/APhysPolA.117.34
  3. Konenkamp R, Boedecker K, Lux-Steiner M, Poschenrieder CM, Zenia F, Levy-Clement C, Wagner S, 2000. Thin film semiconductor deposition on free-standing ZnO columns. Appl. Phys. Lett. 77: 2575-2576. doi:10.1063/1.1319187
  4. Singh S, Kaur H, Pathak D, Bedi R.K, 2011. Zinc oxide nanostructures as transparent window layer for photovoltaic application. Dig. Journ. Nanomat. Biostr. 6: 689-698.
  5. Wisz G, Virt I, Sagan P, Potera P, Yavorskyi R, 2017. Structural, optical and electrical properties of zinc oxide layers produced by pulsed laser deposition method. Nanoscale Res. Lett., 12: 253. doi:10.1186/s11671-017-2033-9
  6. Phan TL, Sun Y.K, Vincent R, Cherns D, Nghia NX, Yu SC, 2008. Optical properties of Mn-doped ZnO nanowires. Journ. Korean Phys. Soc., 52: 1633-1636. doi:10.3938/jkps.52.1633
  7. Ryu YR, Lee TS, Lubguban J A, White HW, Park YS, Youn CJ, 2005. ZnO devices: Photodiodes and pp-type field-effect transistors. Appl. Phys. Lett. 87: 153504. doi:10.1063/1.2089176
  8. Ngan PH, Tien NQ, Dat DT, Nho PV, Nghia NX, Yu SC, 2008. Preparation of the transparent conductive ZnO nanomaterial by means of pulsed spray pyrolysis. Journ. Korean Phys. Soc. 52: 1594-1597. doi:10.3938/jkps.52.1594
  9. Özgür Ü, Alivov YaI, Liu C, Teke A, Reshchikov MA, Doğan S, Avrutin V, Cho S-J, Morkoç H, 2005. A comprehensive review of ZnO materials and devices. Journ. Appl. Phys. 98: 041301. doi:10.1063/1.1992666
  10. Khranovskyy V, Eriksson J, Lloyd-Spetznita A, Yakimova R, Hultman L, 2009.Effect of oxygen exposure on the electrical conductivity and gas sensitivity of nanostructured ZnO films. Thin Sol.Films 517: 2073-2078. doi:10.1016/j.tsf.2008.10.037
  11. Lorite I, Rubio-Marcos F, Romero J.J, Fernández J.F, 2009. In situ formation of Mn-doped ZnO aligned structures by rapid heating method. Mat.Lett. 63: 212-214. doi:10.1016/j.matlet.2008.09.058
  12. Girija K.G, Somasundaram K, Topkar A, Vatsa R.K, 2016. Highly selective H2S gas sensor based on Cu-doped ZnO nanocrystalline films deposited by RF magnetron sputtering of powder target. Journ. Alloys Comp. 684: 15-20. doi:10.1016/j.jallcom.2016.05.125
  13. Ya KX, Yin H, De TM, Jing TM, 1998. Analysis of ZnO varistors prepared from nanosize ZnO precursors. Mat. Res. Bull. 33: 1703-1708. doi:10.1016/S0025-5408(98)00160-3
  14. Chopra KL, Major S, and Pandya DK, 1983. Transparent conductors - A status review. Thin Sol. Films 102: 1-46. doi:10.1016/0040-6090(83)90256-0
  15. Arshak K, Corcoran J, Korostynska O, 2005. Gamma radiation sensing properties of TiO2, ZnO, CuO and CdO thick film pn-junctions. Sens. Actuat. A 123-124: 194-198. doi:10.1016/j.sna.2005.01.014
  16. Arora A, Dwivedi VK, George PJ, Sreenivas K, Gupta V, 2008. Zinc oxide thin film-based MEMS acoustic sensor with tunnel for pressure compensation. Sens. Actuat. A, 141: 256-261. doi:10.1016/j.sna.2007.09.016
  17. Look DC, Reynolds DC, Litton CW, Jones RL, Eason DB, Cantwell G, 2002. Characterization of homoepitaxial p-type ZnO grown by molecular beam epitaxy. Appl. Phys. Lett. 81: 1830. doi:10.1063/1.1504875
  18. Cho S, 2009. Effects of growth temperature on the properties of ZnO thin films grown by radio-frequency magnetron sputtering. Trans. Elect. Electron.Mat. 10: 185-188. doi:10.4313/TEEM.2009.10.6.185
  19. Tan ST, Chen BJ, Sun XW, Fan WJ, Kwok HS, Zhang XH, Chua SJ, 2005. Blue shift of optical band gap in ZnO thin films grown by metal-organic chemical-vapor deposition. Journ. Appl. Phys. 98: 013505. doi:10.1063/1.1940137
  20. Kayani ZN, Qbal M, Riaz S, Zia R, Naseem S, 2015. Fabrication and properties of zinc oxide thin film prepared by sol-gel dip coating method. Mat. Sci.-Pol. 33: 515-520. doi:10.1515/msp-2015-0085
  21. Srinivasan G, Gopalakrishnan N, Yu YS, Kesavamoorthy R, Kumar J, 2008.Influence of post-deposition annealing on the structural and optical properties of ZnO thin films prepared by sol-gel and spin-coating method. Superlatt.Microstr. 43: 112-118. doi:10.1016/j.spmi.2007.07.032
  22. Dalchiele EA, Giorgi P, Marotti R, Martín EF, Ayouci R, Leinen D, 2001. Electrodeposition of ZnO thin films on n-Si(1 0 0). Sol.Ener.Mat. Sol.Cells 70: 245-254. doi:10.1016/S0927-0248(01)00065-4
  23. Nadarajah K, Chee CY, Tan CY, 2013. Influence of annealing on properties of spray deposited ZnO thin films. Journ.Nanomat. (Article ID 146382). doi:10.1155/2013/146382
  24. Senthilkumaar S, Rajendran K, Banerjee S, 2008. Influence of Mn doping on the microstructure and optical property of ZnO. Mat.Sci.Semicond.Proc. 11: 6-12. doi:10.1016/j.mssp.2008.04.005
  25. Liua Y, Yang J, 2009. Effects of Cr-doping on the optical and magnetic properties in ZnO nanoparticles prepared by sol-gel method. Journ.Alloys Comp. 486: 835-838. doi:10.1016/j.jallcom.2009.07.076
  26. Olvera MD, Maldonado A, Asomoza R, Lira MM, 2000. Chemical stability of doped ZnO thin films. Journ. Mat.Sci.: Mat. Electron. 11: 1-5.
  27. Sato K, Yoshida HK, 2001. Stabilization of ferromagnetic states by electron doping in Fe-, Co- or Ni-Doped ZnO. Jap. Journ.Appl.Phys. 40: L334-L336. doi:10.1143/JJAP.40.L334
  28. Benramache S, Benhaoua B, Chabane F, 2012. Effect of substrate temperature on the stability of transparent conducting cobalt doped ZnO thin films. Journ.Semicond. 33: 093001-1. doi:10.1088/1674-4926/33/9/093001
  29. Dietl T, Ohno H, Matsukura F, 2001.Hole-mediated ferromagnetism in tetrahedrally coordinated semiconductors. Phys.Rev.B 63: 195205. doi:10.1103/PhysRevB.63.195205
  30. Mandal S.K, Nath T.K, 2006. Microstructural, magnetic and optical properties of ZnO:Mn (0.01 ≤ x ≤ 0.25) epitaxial diluted magnetic semiconducting films. Thin Sol.Films 515: 2535-2541. doi:10.1016/j.tsf.2006.03.032
  31. Singhal RK, Dhawan M, Kumar S, Dolia SN, Xing YT, Saitovitch E, 2009. Room temperature ferromagnetism in Mn doped dilute ZnO semiconductor; an electronic structure stud. Physica B 404: 3275-3280. doi:10.1016/j.physb.2009.07.100
  32. Iqbal A, Ahmood A, Khan TM, Ahmed E, 2013. Structural and optical properties of Cr doped ZnO crystalline thin films deposited by reactive electron beam evaporation technique. Prog.Nat.Sci.: Mat.Intern. 23: 64-69. doi:10.1016/j.pnsc.2013.01.010
  33. Ramani RV, Ramani BM, Saparia AD, Savaliya C, Rathod KN, Markna JH, 2018. Cr-ZnO nanostructured thin film coating on borosilicate glass by cost effective sol-gel dip coating method. Ain Shams Engin. Journ. 9: 777-782. doi:10.1016/j.asej.2016.04.015
  34. Maldonado A, Mall'En-Hern'Andez SA, Vega-P'Erez J, Olvera M L, Tirado-Guerra S, 2009. Chromium doped zinc oxide thin films deposited by chemical spray used in photo-catalysis and gas sensing. Rev.Mexic.Fis. S55: 90-94.
  35. Iqbal T, Ghazal S, Atiq S, Khalid NR, Majid A, Afsheen S, Niaz NA, 2016. Influence of manganese on structural, dielectric and magnetic properties of ZnO nanoparticles. Digest Journ. Nanomat. Biostr. 11: 899 - 908.
  36. Mondal S, Bhattacharyya SR , Mitra P, 2013.Preparation of manganese-doped ZnO thin films and their characterization. Bull.Mat.Sci. 36: 223-229. doi:10.1007/s12034-013-0462-3
  37. Cao P, Bai Y, 2013.Structural and optical properties of ZnCoO thin film prepared by electrodeposition. Advan.Mat.Res. 781-784: 323-326. doi:10.4028/www.scientific.net/AMR.781-784.323
  38. Vuichyk MV, Tsybrii ZF, Lavoryk SR, Svezhentsova KV, Virt IS, Chizhov A, 2014. Morphologic and optical characterization of ZnO:Co thin films grown by PLD. Semicond.Phys.Quant.Electron. & Optoelectron. 17: 80-84. doi:10.15407/spqeo17.01.080
  39. Viezbicke BD, Patel S, Davis BE, Birnie DP, 2015. Evaluation of the Tauc method for optical absorption edge determination: ZnO thin films as a model system. Phys.Stat.Sol. B, 252: 1700-1710. doi:10.1002/pssb.201552007
  40. Nithya N, Radhakrishnan S, 2012. Effect of thickness on the properties ZnO thin films. Advan.Appl.Sci.Res. 3: 4041-4047.
  41. Khan ZR, Khan MS, Zulfequar M, Khan MoS, 2011. Optical and structural properties of ZnO thin films fabricated by sol-gel method. Mat.Sci.Appl. 2: 340-345 doi:10.4236/msa.2011.25044
  42. Trapalis A, Heffernan J, Farrer I, Sharman J, Kean A, 2016. Structural, electrical, and optical characterization of as grown and oxidized zinc nitride thin films. Journ.Appl. Phys. 120: 205102. doi:10.1063/1.4968545
(c) Ukrainian Journal of Physical Optics