Ukrainian Journal of Physical Optics 


Number  1, Volume 6,  2005

Home page
 
 

Other articles 
in this issue


The Nature of Central Peak of Light Scattering in Glass-Like Media 
Zelenin S.V.

Research Institute of Physics, Odessa National University, 27 Pasteur St., 65026 Odessa, Ukraine

download full version

A theory describing frequency and temperature dependences of the quasielastic peak (QEP) of low-frequency Raman scattering in glass-like materials is suggested. It is based on the ideas about dynamical fluctuations of defects concentration at the internal surface of the glass consisting of nanometer-size clusters. The fluctuations lead to variations of the Laplace pressure in the clusters and, as a consequence, the appearance of QEP. The theory results in a good quantitative description of the experimental low-frequency Raman spectra, which could not be achieved in framework of the known double-level system model.

Key words: glass-like materials, Raman scattering, quasielastic peak, nanoclusters, adatoms.

doi 10.3116/16091833/6/1/6/2005

1. Martin AJ, Brenig W, 1974. Phys. Stat. Solidi (b) 63: 163.
2. Malinovsky VK, Novikov VN, Sokolov AP, 1993. Usp. Fiz. Nauk. 163: 119.
3. Malinovsky VK, 1999. Fiz. Tverd. Tela. 41: 805.
4. Roling B, Ingram MD, Lange M, Funke K, 1997. Phys. Rev. B 56: 13619.
        doi:10.1103/PhysRevB.56.13619 http://dx.doi.org/10.1103/PhysRevB.56.13619
5. Mikhailov MD, Tveryanovich US, Turkina EU, 1998. Chemistry of glasses and alloys. St.-Petersburg University Press, 143.
6. Bondarev VN, Zelenin SV, 2003. Fiz. Tverd. Tela. 45: 790.
7. Carini G, Federico M, Fontana A, Saunders GA, 1993. Phys. Rev. B 47: 3005.
        doi:10.1103/PhysRevB.47.3005 http://dx.doi.org/10.1103/PhysRevB.47.3005
8. Theodorakoulos N, Jäckle J, 1976. Phys. Rev. B 14: 2637.
        doi:10.1103/PhysRevB.14.2637 http://dx.doi.org/10.1103/PhysRevB.14.2637
9. Nemanich RJ, 1977. Phys. Rev. B 16: 1655.
        doi:10.1103/PhysRevB.16.1655 http://dx.doi.org/10.1103/PhysRevB.16.1655
10. Tatsumisago M, Torata N, Saito T, Minami TJ, 1996. Non-Cryst. Solids 196: 193.
11. Bondarev VN, Zelenin SV, 2003. Elektrokhimiya 39: 501.
12. Frenkel YaI, 1958. Selected works, USSR Academy of Science publishing 2: 598p.
13. Landau LD, Lifshitz EM, 1976. Statistical physics, part 1. Moscow, Nauka: 584p.

Home | Instructions to Authors | Editorial Board | Meetings & Exhibitions